purity ozone
is desired (is necessary), liquid ozone is used. 4. When
water is boiling,
vapour is formed.
6
. The normal atmospheric
pressure
is 760 mm. 7. The characteristic odour o f ozone is detcctablc by
nose.
8
. This odour
provides (gives)
a warning (a signal) of toxicity. 9. On
exposure to oxygen metals arc oxidized.
10
. Gaseous ozone
possesses
four resonance structures. 11. Elcctrophilic nature o f ozone is
accounted
fo r (explained by) this fact.
Слова к тексту:
silent discharge — тнхнй разряд; require — требовать; environment —
окружающая среда; pass through a vessel — проходить через сосуд; bond —
связь; rat — крыса; undergo — подвергаться
Text 5 В
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Ozone: Properties, Toxicity, and Applications
Common methods for ozone generation arc ultraviolet radiation, silent
electric arc discharge and electrolysis. The unltraviolct radiation technique
is used only when relatively low concentrations arc required, c. g. for
environmental study. The electrolysis of water is not widely used bccausc
of its low efficiency. So far, the action of silent clcctric discharge on oxygen
is the most common method for the production of ozone. It gives a yield of
6
% by weight of ozone.
When high purity or quantity of ozone is desired, it is possible to use
liquid ozone. The ozonc-oxygcn mixture from one of the above methods
is passed through a vessel at liquid oxygen temperature (-183°C). Because
o f the large difference in the vapour pressure of ozone and oxygen, oxygen
is pumped off from the mixture whereas ozone is liquefied. Liquid ozone
is then vaporized from the concentrated system for further use.
Ozone is a colourless gas with characteristic odour which is detectable
by nose and provides a warning o f toxic exposure. The ozone molecule is
non-linear with a bond angle o f 116°. In contrast to oxygen, gaseous ozone
is diamagnetic and possesses four resonance structures with (III) and (IV)
accounting for its elcctrophilic nature.
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