and also by (he direction in which they rotate the plane o f polarization of
polarized light.
The structure of quartz is closely related
to that of silicic acid, H
4
Si04.
In this acid silicon has ligancy 4, and is surrounded by a tetrahedron or
four
oxygen atoms, with one hydrogen atom attached to each oxygen atom.
Silicic acid, which is a very weak acid, has the property of undergoing
condensation very readily, with elimination of water. If each of the four
hydroxyl groups of a silicic acid molcculc condenses with a similar
hydroxyl group of an adjacent molcculc, eliminating water, a structure is
obtained in which the silicon atom is bonded to four surrounding silicon
atoms by silicon-oxygcn-silicon bonds. This proccss leads to a condensation
product with formula Si02, sincc each silicon atom is surrounded by four
oxygen atoms, and each oxygen atom serves as a neighbour to two silicon
atoms. The structure of quartz and of the other forms of silica is described
as consisting of Si0
4
tetrahedra, and each oxygen atom is a comer of two
o f these tetrahedra. In order to break a crystal of quartz it is necessary to
break some silicon-oxygcn bonds. In this way the structure of quartz
accounts for the hardness of the mineral.
Cristobalitc and tridymitc arc similarly made from Si0
4
tetrahedra fused
together by sharing oxygen atoms, with, however, different arrangements
o f the tetrahedra in space from that of quartz. Tridymitc resembles ordinary
icc in structure, with silicon atoms in the oxygcn-atom positions; cristobalitc
similarly resembles cubic icc.
Words and Word-Combinations to Be Memorized
account for, adjacent, arrangement, attach, closely, crystalline, deposit,
dioxide, formula, fuse, granite, group, hydroxyl, identify, mostly, neighbour,
position, quartz, be related to, serve, share, silicon, similarly, since, space,
surround, together, undergo, weak
Ex. 6. Give the Russian equivalents for the following:
next to oxygen, mostly, the most widespread mineral, deposit, a well-
formed crystal, constituent, a hard substancc, identify something, right-
handed, left-handed, rotate, the plane of polarization, polarized light, be
closely related to, be surrounded by, a weak acid, undergo condensation, a
hydroxyl group, an adjaccnt molecule, be bonded to, lead to, condensation
product, neighbour, in order to break a crystal, account for, be fused
together, share oxygen atoms, ordinary icc, resemble smth. in structure
Ex. 7. Give the English equivalents for the following:
диоксид кремния, встречаться в природе, вращать плоскость по
ляризации, структура кварца, быть тесно связанным с, окружать, при
соединить к атому, очень слабая кислота, подвергаться конденса
ции, очень легко, каждая из гидроксильных групп, молекула кислоты,
связь, вести к, продукт конденсации, разорвать связь, таким образом,
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