ANNOTATION: The article considers some issues of creation of new polymer
modified binders for wood-based materials. As the modifier used local raw material
resources.The optimal amount of added modifier and its effect on physico-mechanical
properties of plates. Besides the toxic free formaldehyde of the plates. As a result of
the investigations it was revealed the optimum amount of modifier is achieved where
417
wakiephysico-mechanical properties of the product and waveny dependence of the
modifier-free formaldehyde. Obtained wood boards completely meet the requirements
of the standard predevlyaemye to the plates.
The main physical and mechanical
properties of particle boards are water absorption, swelling, ultimate strength in static
bending and ultimate strength in fracture perpendicular to the layer. These indicators
of the properties of the boards largely depend on the quality and properties of the binder
polymer, on its degree of curing during the production of boards.To obtain particle
boards, the following types of work were performed: Preparation of gossypol resin by
dissolving it in white spirit in a 1: 1 ratio. The wood was crushed to a length of 2-3 cm
and a width of 0.2-0.4 cm. The accepted dimension of chips was determined according
to GOST for chips used for the production of board materials. The total amount of
binder used was 10% of absolutely dry chips. The binder modification was carried out
at a temperature of 60 ° C and a modification time of 180 minutes. Binder concentration
KF-MT-63%. Pressing temperature - 170 ° C, pressing time - 0.30 mm / min, plate
thickness 1.60 ± 1 cm, pressure - 2.5 MPa.
The study of the effect
of gossypol resin on the physicochemical urea-formaldehyde binder showed that the
modifier has a positive effect on all its properties, such as hydrophobicity, heat
resistance, adizability, etc. Now it was necessary to conduct research on a specific
product, where different results could be obtained.
In this work, it was necessary to compare the
results of studying the effect of the content of the modifier in the binder on the physical
and mechanical properties of the plates, i.e. the results of experiments with a binder
were transferred to the finished product - chipboard.
To determine the amount of gossypol resin, it was introduced
in an amount of 0.5%; 10%; 15%, 20%; 30% of the dry residue of the resin to determine
the optimal content. As the results of the study showed, the introduction of the modifier
affects the quality of the slab, where the ultimate strength in static bending showed
that, in comparison with the unmodified composition, in specimens with gossypol resin
the flexural strength increased from 13.3 MPa with the introduction of 10% modifier
to 19.2 MPa. A further increase in the content of gossypol resin leads to a decrease in
418
the studied indicator. It is known that the flexural strength depends mainly on the
adhesion strength of the particle particles, therefore, we can talk about the positive
effect of modification on the property of the resin, which leads to a more active
interaction of the functional groups of the binder and filler.
The same picture is observed when testing
specimens by breaking a perpendicular plate. Boards based on a modified binder, the
breaking strength of the plate is significantly higher than that of unmodified ones, and
the best result of 0.50 MPa also corresponds to a 10% content of gossypol resin in the
composition. A further increase in the amount of modifier leads to a decrease in tensile
strength. This is probably due to an increase in low molecular weight substances in the
composition, which negatively affects the adhesiveness of the chips.
The increase in tensile strength in specimens based on a modified binder is
explained by an increase in the curing of the binder, its interaction with filler particles,
and the strength of bond adhesion at the adhesive-substrate interface. The introduction
of gossypol resin, which contains 10-12% of nitrogen-containing substances, also leads
to an increase in adhesive ability, and carboxyl groups deepen the degree of curing of
the resin.
The increase in tensile strength in
specimens based on a modified binder is explained by an increase in the curing of the
binder, its interaction with filler particles, and the strength of bond adhesion at the
adhesive-substrate interface. The introduction of gossypol resin, which contains 10-
12% of nitrogen-containing substances, also leads to an increase in adhesive ability,
and carboxyl groups deepen the degree of curing of the resin. The study of the effect
of the modifier on the water absorption of particle boards showed that the boards
obtained without the modifier had a water absorption of 135%, and when gossypol
resin was added to the binder, it significantly decreased, and the lowest water
absorption value is observed with a modifier content of 10-15%.
419
Достарыңызбен бөлісу: |